Volume 37
Main Index

Issue 01

Supramolecular Metal−Organometallic Coordination Networks Based on Quinonoid π-Complexes Moonhyun Oh, Gene B. Carpenter, and Dwight A. Sweigart pp 1–11 DOI: 10.1021/ar030175o

Photoreceptor Proteins, “Star Actors of Modern Times”:  A Review of the Functional Dynamics in the Structure of Representative Members of Six Different Photoreceptor Families Michael A. van der Horst and Klaas J. Hellingwerf pp 13–20 DOI: 10.1021/ar020219d

Recent Advances in Synthetic Transformations Mediated by Cerium(IV) Ammonium Nitrate Vijay Nair, Lakshmi Balagopal, Roshini Rajan, and Jessy Mathew pp 21–30 DOI: 10.1021/ar030002z

Recent Highlights in Electrophilic Fluorination with 1-Chloromethyl-4-fluoro- 1,4-diazoniabicyclo[2.2.2]octane Bis(tetrafluoroborate) Rajendra P. Singh and Jean'ne M. Shreeve pp 31–44 DOI: 10.1021/ar030043v

Dynamics of Antioxidant Action of Vitamin E Etsuo Niki and Noriko Noguchi pp 45–51 DOI: 10.1021/ar030069m

Petroleomics:  The Next Grand Challenge for Chemical Analysis Alan G. Marshall and Ryan P. Rodgers pp 53–59 DOI: 10.1021/ar020177t

A Fluorescent Intercalator Displacement Assay for Establishing DNA Binding Selectivity and Affinity Winston C. Tse and Dale L. Boger pp 61–69 DOI: 10.1021/ar030113y

Issue 02

Copper Binding in the Prion Protein Glenn L. Millhauser pp 79–85 DOI: 10.1021/ar0301678

New Progress in the Chemistry of Stable Metallaaromatic Compounds of Heavier Group 14 Elements Norihiro Tokitoh pp 86–94 DOI: 10.1021/ar020093k

Laser-Assisted High-Pressure Chemical Reactions Roberto Bini pp 95–101 DOI: 10.1021/ar030015c

The Direct Catalytic Asymmetric Mannich Reaction Armando Córdova pp 102–112 DOI: 10.1021/ar030231l

Effective Molarities in Supramolecular Catalysis of Two-Substrate Reactions Roberta Cacciapaglia, Stefano Di Stefano, and Luigi Mandolini pp 113–122 DOI: 10.1021/ar020076v

Loops, Linkages, Rings, Catenanes, Cages, and Crowders:  Entropy-Based Strategies for Stabilizing Proteins Huan-Xiang Zhou pp 123–130 DOI: 10.1021/ar0302282

Tyrosine-Derived Quinone Cofactors Minae Mure pp 131–139 DOI: 10.1021/ar9703342

Issue 03

Communicating Original Research in Chemistry and Related Sciences Lorrin R. Garson pp 141–148 DOI: 10.1021/ar0300017

Understanding the Importance of Protein Structure to Nature's Routes for Divergent Evolution in TIM Barrel Enzymes Eric L. Wise and Ivan Rayment pp 149–158 DOI: 10.1021/ar030250v

Molybdenum-Catalyzed Asymmetric Allylic Alkylations Oscar Belda and Christina Moberg pp 159–167 DOI: 10.1021/ar030239v

Asymmetric Synthesis and Organometallic Chemistry of Functionalized Phosphines Containing Stereogenic Phosphorus Centers Pak-Hing Leung pp 169–177 DOI: 10.1021/ar030008o

Paramagnetic Cp/Dithiolene Complexes as Molecular Hinges:  Interplay of Metal/Ligand Electronic Delocalization and Solid-State Magnetic Behavior Marc Fourmigué pp 179–186 DOI: 10.1021/ar030214w

Homolytic Cleavage and Aggregation Processes in Cyclopentadienylchromium Chemistry Zhiqiang Weng and Lai Yoong Goh pp 187–199 DOI: 10.1021/ar030003r

Generation and Mesolytic Dynamics of Organoselenane and Selenosilane Radical Ions:  Development of Mechanistically Interesting and Synthetically Useful Chemistry Ganesh Pandey and Smita R. Gadre pp 201–210 DOI: 10.1021/ar030037z

Issue 04

Superelectrophilic Solvation George A. Olah and Douglas A. Klumpp pp 211–220 DOI: 10.1021/ar020102p

Synchrotron Radiolysis and Mass Spectrometry:  A New Approach to Research on the Actin Cytoskeleton Jing-Qu Guan, Steven C. Almo, and Mark R. Chance pp 221–229 DOI: 10.1021/ar0302235

Do New Century Catalysts Unravel the Mechanism of Stereocontrol of Old Ziegler−Natta Catalysts? Paolo Corradini, Gaetano Guerra, and Luigi Cavallo pp 231–241 DOI: 10.1021/ar030165n

Asymmetric Transfer of Carbenes with Phenyliodonium Ylides Paul Müller pp 243–251 DOI: 10.1021/ar0202619

Fe(III) and Co(III) Centers with Carboxamido Nitrogen and Modified Sulfur Coordination:  Lessons Learned from Nitrile Hydratase Todd C. Harrop and Pradip K. Mascharak pp 253–260 DOI: 10.1021/ar0301532

Vibrational Energy Flow and Chemical Reactions M. Gruebele and P. G. Wolynes pp 261–267 DOI: 10.1021/ar030230t

Ultrasensitive and Quantitative Analyses from Combined Separations−Mass Spectrometry for the Characterization of Proteomes Richard D. Smith, Yufeng Shen, and Keqi Tang pp 269–278 DOI: 10.1021/ar0301330

Issue 05

Structural Basis of Single-Stranded RNA Recognition Ana C. Messias and Michael Sattler pp 279–287 DOI: 10.1021/ar030034m

Toward Ideal (Trans)Esterification by Use of Fluorous Distannoxane Catalysts Junzo Otera pp 288–296 DOI: 10.1021/ar030146d

β-SultamsMechanism of Reactions and Use as Inhibitors of Serine Proteases Michael I. Page pp 297–303 DOI: 10.1021/ar0200899

Communication Pathways between the Nucleotide Pocket and Distal Regulatory Sites in Protein Kinases Lilly Wong, Patricia A. Jennings, and Joseph A. Adams pp 304–311 DOI: 10.1021/ar020128g

Aqueous RAFT Polymerization:  Recent Developments in Synthesis of Functional Water-Soluble (Co)polymers with Controlled Structures Charles L. McCormick and Andrew B. Lowe pp 312–325 DOI: 10.1021/ar0302484

Small Is Different:  Shape-, Size-, and Composition-Dependent Properties of Some Colloidal Semiconductor Nanocrystals Mostafa A. El-Sayed pp 326–333 DOI: 10.1021/ar020204f

Bond Strengths of Toluenes, Anilines, and Phenols:  To Hammett or Not Derek A. Pratt, Gino A. DiLabio, Peter Mulder, and K. U. Ingold pp 334–340 DOI: 10.1021/ar010010k

Issue 06

Nanomaterials Based on Phosphorus Dendrimers Anne-Marie Caminade and Jean-Pierre Majoral pp 341–348 DOI: 10.1021/ar020077n

Breaking, Making, and Twisting of Chemical Bonds in Gas, Liquid, and Nanocavities Abderrazzak Douhal pp 349–355 DOI: 10.1021/ar030247b

Rapid Photochemical Cross-LinkingA New Tool for Studies of Metastable, Amyloidogenic Protein Assemblies Gal Bitan and David B. Teplow pp 357–364 DOI: 10.1021/ar000214l

Evolution of Dithiane-Based Strategies for the Construction of Architecturally Complex Natural Products Amos B. Smith, III and Christopher M. Adams pp 365–377 DOI: 10.1021/ar030245r

Transient Species in the Stepwise Interconversion of NADH and NAD+ Jerzy Gȩbicki, Andrzej Marcinek, and Jacek Zielonka pp 379–386 DOI: 10.1021/ar030171j

Boron-Mediated Aldol Reaction of Carboxylic Esters Atsushi Abiko pp 387–395 DOI: 10.1021/ar030249w

Knowledge of the Proposed Chemical Mechanism of Action and Cytochrome P450 Metabolism of Antimalarial Trioxanes Like Artemisinin Allows Rational Design of New Antimalarial Peroxides Gary H. Posner and Paul M. O'Neill pp 397–404 DOI: 10.1021/ar020227u

Ca2+-Regulated Photoproteins:  Structural Insight into the Bioluminescence Mechanism Eugene S. Vysotski and John Lee pp 405–415 DOI: 10.1021/ar0400037

Issue 07

The Conversation Continues I John D. Roberts pp 417–418 DOI: 10.1021/ar030293b

The Conversation Continues II Andrew Streitwieser pp 419–419 DOI: 10.1021/ar040042i

Reactions of the Diiron Enzyme Stearoyl-Acyl Carrier Protein Desaturase Brian G. Fox, Karen S. Lyle, and Corina E. Rogge pp 421–429 DOI: 10.1021/ar030186h

Role of Glycosaminoglycans in Cellular Communication Robert J. Linhardt and Toshihiko Toida pp 431–438 DOI: 10.1021/ar030138x

Metal Ion Modulated Electron Transfer in Photosynthetic Proteins Lisa M. Utschig and Marion C. Thurnauer pp 439–447 DOI: 10.1021/ar020197v

Origin, Control, and Application of Supramolecular Chirogenesis in Bisporphyrin-Based Systems Victor V. Borovkov, Guy A. Hembury, and Yoshihisa Inoue pp 449–459 DOI: 10.1021/ar0302437

Combined Spectroscopic/Computational Studies on Fe- and Mn-Dependent Superoxide Dismutases:  Insights into Second-Sphere Tuning of Active Site Properties Timothy A. Jackson and Thomas C. Brunold pp 461–470 DOI: 10.1021/ar030272h

Determining the Geometries of Transition States by Use of Antihydrophobic Additives in Water Ronald Breslow pp 471–478 DOI: 10.1021/ar040001m

Progress in the Chemistry of Metallabenzynes Guochen Jia pp 479–486 DOI: 10.1021/ar0201512

Issue 08

Asymmetric Organocatalysis K. N. Houk, Benjamin List pp 487–487 DOI: 10.1021/ar040216w

Organocatalytic Asymmetric Epoxidation of Olefins by Chiral Ketones Yian Shi pp 488–496 DOI: 10.1021/ar030063x

Ketone-Catalyzed Asymmetric Epoxidation Reactions Dan Yang pp 497–505 DOI: 10.1021/ar030065h

The Enantioselective Synthesis of α-Amino Acids by Phase-Transfer Catalysis with Achiral Schiff Base Esters Martin J. O'Donnell pp 506–517 DOI: 10.1021/ar0300625

Asymmetric Phase-Transfer Catalysis Utilizing Chiral Quaternary Ammonium Salts:  Asymmetric Alkylation of Glycine Imines Barry Lygo and Benjamin I. Andrews pp 518–525 DOI: 10.1021/ar030058t

Asymmetric Organocatalysis of Structurally Well-Defined Chiral Quaternary Ammonium Fluorides Takashi Ooi and Keiji Maruoka pp 526–533 DOI: 10.1021/ar030060k

Nucleophilic Carbenes in Asymmetric Organocatalysis Dieter Enders and Tim Balensiefer pp 534–541 DOI: 10.1021/ar030050j

Asymmetric Catalysis with “Planar-Chiral” Derivatives of 4-(Dimethylamino)pyridine Gregory C. Fu pp 542–547 DOI: 10.1021/ar030051b

Enamine Catalysis Is a Powerful Strategy for the Catalytic Generation and Use of Carbanion Equivalents Benjamin List pp 548–557 DOI: 10.1021/ar0300571

Theory of Asymmetric Organocatalysis of Aldol and Related Reactions:  Rationalizations and Predictions Christophe Allemann, Ruth Gordillo, Fernando R. Clemente, Paul Ha-Yeon Cheong, and K. N. Houk pp 558–569 DOI: 10.1021/ar0300524

Design of Acid−Base Catalysis for the Asymmetric Direct Aldol Reaction Susumu Saito and Hisashi Yamamoto pp 570–579 DOI: 10.1021/ar030064p

Enamine-Based Organocatalysis with Proline and Diamines:  The Development of Direct Catalytic Asymmetric Aldol, Mannich, Michael, and Diels−Alder Reactions Wolfgang Notz, Fujie Tanaka, and Carlos F. Barbas, III pp 580–591 DOI: 10.1021/ar0300468

Advances in the Catalytic, Asymmetric Synthesis of β-Lactams Stefan France, Anthony Weatherwax, Andrew E. Taggi, and Thomas Lectka pp 592–600 DOI: 10.1021/ar030055g

In Search of Peptide-Based Catalysts for Asymmetric Organic Synthesis Scott J. Miller pp 601–610 DOI: 10.1021/ar030061c

Catalytic, Asymmetric Sulfur Ylide-Mediated Epoxidation of Carbonyl Compounds:  Scope, Selectivity, and Applications in Synthesis Varinder K. Aggarwal and Caroline L. Winn pp 611–620 DOI: 10.1021/ar030045f

Asymmetric Organic Catalysis with Modified Cinchona Alkaloids Shi-Kai Tian, Yonggang Chen, Jianfeng Hang, Liang Tang, Paul McDaid, and Li Deng pp 621–631 DOI: 10.1021/ar030048s

Issue 09

On the Mechanism of Stereoselection in Rh-Catalyzed Asymmetric Hydrogenation:  A General Approach for Predicting the Sense of Enantioselectivity Ilya D. Gridnev and Tsuneo Imamoto pp 633–644 DOI: 10.1021/ar030156e

Olefin Epoxidation with Inorganic Peroxides. Solutions to Four Long-Standing Controversies on the Mechanism of Oxygen Transfer Dirk V. Deubel, Gernot Frenking, Philip Gisdakis, Wolfgang A. Herrmann, Notker Rösch, and Jörg Sundermeyer pp 645–652 DOI: 10.1021/ar0400140

Catalytic C−C Bond Formation via Capture of Hydrogenation Intermediates Hye-Young Jang and Michael J. Krische pp 653–661 DOI: 10.1021/ar020108e

Comparisons between Mammalian and Artificial Olfaction Based on Arrays of Carbon Black−Polymer Composite Vapor Detectors Nathan S. Lewis pp 663–672 DOI: 10.1021/ar030120m

Organolanthanide-Catalyzed Hydroamination Sukwon Hong and Tobin J. Marks pp 673–686 DOI: 10.1021/ar040051r

The Chemistry of Vicinal Tricarbonyls and Related Systems Harry H. Wasserman and Jonathan Parr pp 687–701 DOI: 10.1021/ar0300221

Photoprocesses in Microaggregates Frank H. Quina, Eduardo A. Lissi pp 703–710 DOI: 10.1021/ar030152+

Synthetic Molecules as Antibody Replacements Thomas Kodadek, M. Muralidhar Reddy, Hernando J. Olivos, Kiran Bachhawat-Sikder, and Prasanna G. Alluri pp 711–718 DOI: 10.1021/ar030145l

Iron−Sulfur Cluster Biosynthesis:  Toward an Understanding of Cellular Machinery and Molecular Mechanism Sheref S. Mansy and J. A. Cowan pp 719–725 DOI: 10.1021/ar0301781

Vibrational and Electronic Spectra of Neutral and Ionic Combustion Reaction Intermediates Trapped in Rare-Gas Matrixes Marilyn E. Jacox pp 727–734 DOI: 10.1021/ar030088w

Issue 10

Directly Linked Porphyrin Arrays with Tunable Excitonic Interactions Dongho Kim and Atsuhiro Osuka pp 735–745 DOI: 10.1021/ar030242e

Phosphoryl Transfer Enzymes and Hypervalent Phosphorus Chemistry Robert R. Holmes pp 746–753 DOI: 10.1021/ar040053b

Metal-Assembled Modular Proteins:  Toward Functional Protein Design Martin A. Case and George L. McLendon pp 754–762 DOI: 10.1021/ar960245+

Transformations of Molecules and Secondary Building Units to Materials:  A Bottom-Up Approach R. Murugavel, M. G. Walawalkar, Meenakshi Dan, H. W. Roesky, and C. N. R. Rao pp 763–774 DOI: 10.1021/ar040083e

Unraveling the Structure and Mechanism of Acetyl-Coenzyme A Synthase Eric L. Hegg pp 775–783 DOI: 10.1021/ar040002e

Understanding Nucleic Acids Using Synthetic Chemistry Steven A. Benner pp 784–797 DOI: 10.1021/ar040004z

Exploiting the Synergy between Coordination Chemistry and Molecular Imprinting in the Quest for New Catalysts Jennifer J. Becker and Michel R. Gagné pp 798–804 DOI: 10.1021/ar000102u

The Virtue of the Multifunctional Triazene Linkers in the Efficient Solid-Phase Synthesis of Heterocycle Libraries Stefan Bräse pp 805–816 DOI: 10.1021/ar0200145

Allylsilanes and Vinylsilanes from Silylcupration of Carbon−Carbon Multiple Bonds:  Scope and Synthetic Applications Asunción Barbero and Francisco J. Pulido pp 817–825 DOI: 10.1021/ar0400490

Ca2+-Regulated Photoproteins:  Structural Insight into the Bioluminescence Mechanism Eugene S. Vysotski and John Lee pp 826–826 DOI: 10.1021/ar040213j

Issue 11

Quinonoid Metal Complexes:  Toward Molecular Switches Andrea Dei, Dante Gatteschi, Claudio Sangregorio, and Lorenzo Sorace pp 827–835 DOI: 10.1021/ar0200706

Copolymerization of CO2 and Epoxides Catalyzed by Metal Salen Complexes Donald J. Darensbourg, Ryan M. Mackiewicz, Andrea L. Phelps, and Damon R. Billodeaux pp 836–844 DOI: 10.1021/ar030240u

DNA-Templated Assembly of Helical Cyanine Dye Aggregates:  A Supramolecular Chain Polymerization Kristen C. Hannah and Bruce A. Armitage pp 845–853 DOI: 10.1021/ar030257c

Electron-Transfer Processes of Cytochrome c at Interfaces. New Insights by Surface-Enhanced Resonance Raman Spectroscopy Daniel H. Murgida and Peter Hildebrandt pp 854–861 DOI: 10.1021/ar0400443

Chiral Molecular Tweezers Michael Harmata pp 862–873 DOI: 10.1021/ar030164v

Molecular Aspects of the Transport and Toxicity of Ochratoxin A Jian Dai, Gyungse Park, Jennifer L. Perry, Yuri V. Il'ichev, Daniel A. J. Bow, John B. Pritchard, Virginie Faucet, Annie Pfohl-Leszkowicz, Richard A. Manderville, and John D. Simon pp 874–881 DOI: 10.1021/ar0302134

Attachment Chemistry of Organic Molecules on Si(111)-7 × 7 Feng Tao and Guo Qin Xu pp 882–893 DOI: 10.1021/ar0400488

Singlet Oxygen Microscope:  From Phase-Separated Polymers to Single Biological Cells John W. Snyder, Ingo Zebger, Zhan Gao, Lars Poulsen, Peter K. Frederiksen, Esben Skovsen, Sean P. McIlroy, Markus Klinger, Lars Klembt Andersen, and Peter R. Ogilby pp 894–901 DOI: 10.1021/ar040075y

Microbial Detoxification of Superoxide:  The Non-Heme Iron Reductive Paradigm for Combating Oxidative Stress Donald M. Kurtz, Jr. pp 902–908 DOI: 10.1021/ar0200091

Heterogeneous Enantioselective Hydrogenation over Cinchona Alkaloid Modified Platinum:  Mechanistic Insights into a Complex Reaction Thomas Bürgi and Alfons Baiker pp 909–917 DOI: 10.1021/ar040072l

Issue 12

Selectivity Control in Electron Spin Inversion Processes:  Regio- and Stereochemistry of Paternò−Büchi Photocyclo- additions as a Powerful Tool for Mapping Intersystem Crossing Processes Axel G. Griesbeck, Manabu Abe, and Samir Bondock pp 919–928 DOI: 10.1021/ar040081u

Monitoring Protein Folding at Atomic Resolution Thallapuranam Krishnaswamy S. Kumar and Chin Yu pp 929–936 DOI: 10.1021/ar020156z

A Carbon Nanotube-Based Coulter Nanoparticle Counter Takashi Ito, Li Sun, Ronald R. Henriquez, and Richard M. Crooks pp 937–945 DOI: 10.1021/ar040108+

Some Interesting Things about Polysiloxanes James E. Mark pp 946–953 DOI: 10.1021/ar030279z

Transient 2H-Phospholes as Powerful Synthetic Intermediates in Organophosphorus Chemistry François Mathey pp 954–960 DOI: 10.1021/ar030118v

Evolution of a Practical Total Synthesis of Ciguatoxin CTX3C Masayuki Inoue and Masahiro Hirama pp 961–968 DOI: 10.1021/ar0301577

A Paradigm Change in Assembling OH Functionalities on Metal Centers Herbert W. Roesky, Sanjay Singh, Vojtech Jancik, and Vadapalli Chandrasekhar pp 969–981 DOI: 10.1021/ar0402154

Surfing the Nanowaves:  Progress in Understanding the Gas−Liquid Interface Leon F. Phillips pp 982–988 DOI: 10.1021/ar0401092

A Thermodynamic “Vocabulary” for Metal Ion Interactions in Biological Systems M. T. Rodgers, P. B. Armentrout pp 989–998 DOI: 10.1021/ar0302843

C-type Cytochrome Formation:  Chemical and Biological Enigmas Julie M. Stevens, Oliver Daltrop, James W. A. Allen, and Stuart J. Ferguson pp 999–1007 DOI: 10.1021/ar030266l